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Latest Publications

  1. Structural Details of Carboxylic Acid-based Hydrogen-bonded Organic Frameworks (HOFs)
    Yuto Suzuki, Ichiro Hisaki*
    Polym. J. 2024, 56, 1-16. DOI:
    10.1038/s41428-023-00840-2 Open Access!
    Selected for Cover Picture
  1. Semicontinuous Temperature Cycle-Induced Deracemization Using an Axially Chiral Naphthamide
    Ryusei Oketani,* Riku Naito, Ichiro Hisaki*
    (Org. Process Res. Dev. 2024, in press) DOI: 10.1021/acs.oprd.4c00091
    2024OPRD.jpg
  2. Photo-responsive Hydrogen-Bonded Molecular Networks Capable of Retaining Crystalline Periodicity after Isomerization
    Koki Kasuya, Ryusei Oketani, Souta Matsuda, Hiroyasu Sato, Fumitaka Ishiwari, Akinori Saeki, Ichiro Hisaki*
    (Angew. Chem. Int. Ed. 2024, in press) DOI: 10.1002/anie.202404700 Open Access !
    2024ACIE.jpg
  3. A Hydrogen-Bonded, Hexagonally-Networked, Layered Framework with Large Aperture Designed by Structural Synchronization of a Macrocycle and Supramolecular Synthon
    Hiroki Yoshimura, Ryusei Oketani, Miki Naruoka, Norimitsu Tohnai, Ichiro Hisaki*
    (Precis. Chem. 2024, in press) DOI: 10.1021/prechem.4c00019 Open Access !
    2024PC.jpg
  4. An Expanded Hydrogen-bonded Organic Framework Formed by A Tetrakis(terphenyl)ethene Derivative
    Mao Yamaguchi, Mario de la Hoz Tomás, Ayano Fujiwara, Ryusei Oketani, Kohei Okubo, Kouki Oka, Norimitsu Tohnai, Abderrazzak Douhal,* Ichiro Hisaki*
    (Bull. Chem. Soc. J. 2024, 97, uoae004) DOI: 10.1093/bulcsj/uoae004
    Selected Paper

    2024BCSJ.jpg
  1. Influence of core size on self-assembled molecular networks composed of C3h-symmetric building blocks through hydrogen bonding interactions: structural features and chirality
    Matsuhiro Maeda, Kotoka Oda, Ichiro Hisaki, Kazukuni Tahara*
    (RSC Adv. 2023, 13, 29512-29521.) DOI: 10.1039/D3RA05762C
  2. Synthesis and Characterization of Dibenzothieno[a,f]pentalenes Enabling Large Antiaromaticity and Moderate Open-shell Character Through a Small Energy Barrier for Bond-shift Valence Tautomerization
    Yusuke, Mizuno, Akira Nogata, Mitsuharu Suzuki, Ken-ichi Nakayama, Ichiro Hisaki, Ryohei Kishi, Akihito Konishi,* Makoto Yasuda*
    (J. Am. Chem. Soc. 2023, 145, 20595-20609.) DOI: 10.1021/jacs.3c07356
  3. Photocyclization Reaction and Related Photodynamics in the Photoproducts of a Tetraphenylethylene Derivative with Bulky Substituents: Unexpected Solvent Viscosity Effect
    Mario de la Hoz Tomás, Mao Yamaguchi, Boiko Cohen, Ichiro Hisaki, Abderrazzak Douhal*
    (Phys. Chem. Chem. Phys. 2023, 25, 18874-18888.) DOI:10.1039/D3CP01295F
  4. Statically and Dynamically Flexible Hydrogen-bonded Frameworks Based on 4,5,9,10-Tetrakis(4-carboxyphenyl)pyrene
    Taito Hashimoto, Ryusei Oketani, Asato Inoue, Kohei Okubo, Kouki Oka, Norimitsu Tohnai, Kazuhide Kamiya, Shuji Nakanishi, Ichiro Hisaki*
    (Chem. Commun. 2003, 59, 7224-7227.) DOI: 10.1039/D3CC01877F Open access!
    2023CC-2ver2.jpgのサムネイル画像

  5. Construction of Hydrogen-bonded Crystalline Frameworks Using Tetrakis(carboxyphenyl)dimethyldihydropyrene Derivative
    Yuna Yamaguchi, Kouki Kasuya, Ryusei Oketani, Ichiro Hisaki*
    (Chem. Lett. 2023, 52, 542-545.) DOI: 10.1246/cl.230198
    2023CL.jpg
  6. Overcoming a Solid Solution System on Chiral Resolution: Combining Crystallization and Enantioselective Dissolution
    Ryusei Oketani,* Koki Shiohara, Ichiro Hisaki*
    (Chem. Commun. 2023, 59, 6175-6178.) DOI: 10.1039/D3CC01352A Open access!
    Selected for Inside Cover Picture


    2023CC-1.jpg
  7. s-Indacene Revisited: Modular Synthesis and Modulation of Structures and Molecular Orbitals of Hexaaryl Derivatives"
    Shun-Jie Jhang, Jayabalan Pandidurai, Ching-Piao Chu, Hirokazu Miyoshi, Yuta Takahara, Masahito Miki, Hikaru Sotome, Hiroshi Miyasaka, Shreyam Chatterjee, Rumi Ozawa, Yutaka Ie, Ichiro Hisaki, Chia-Lin Tsai, Yen-Ju Cheng,* Yoshito Tobe*
    (J. Am. Chem. Soc. 2023, 145, 4716-4729.) DOI: 10.1021/jacs.2c13159
  8. Uniaxial Negative Thermal Expansion Induced by Molecular Rotation in One-Dimensional Supramolecular Assembly with Associated Peculiar Magnetic Behavior
    Kiyonori Takahashi,* Yuki Shirakawa, Hiroki Sakai, Ichiro Hisaki, Shin-ichiro Noro, Tomoyuki Akutagawa, Motohiro Nakano, Takayoshi Nakamura*
    (J. Mater. Chem. C 2023, 11, 1891-1898.) DOI: 10.1039/D2TC04874D
  9. Deciphering the Ultrafast Dynamics of a New Tetraphenylethylene Derivative in Solutions: Charge Separation, Phenyl Rings Rotation and C=C Bond Twisting
    Mario de la Hoz Tomás, Mao Yamaguchi, Boiko Cohen,* Ichiro Hisaki,* Abderrazzak Douhal*
    (Phys. Chem. Chem. Phys. 2023, 25, 1755-1767.) DOI: 10.1039/D2CP05220B
    Selected for 2023 PCCP HOT articles
  10. Isomeric Effect of Naphthyl Spacers on Structures and Properties of Isostructural Porous Crystalline Frameworks
    Yuto Suzuki, Mao Yamaguchi, Ryusei Oketani, Ichiro Hisaki*
    (Mater. Chem. Front. 2023, 7, 106-116.) DOI: 10.1039/D2QM01091G
    Selected for 2022 Materials Chemistry Frontiers HOT articles
    2022MCF.jpg
  11. Single Crystalline, Non-stoichiometric Cocrystals of Hydrogen-Bonded Organic Frameworks
    Taito Hashimoto, Ryusei Oketani, Masaki Nobuoka, Shu Seki, Ichiro Hisaki*
    (Angew. Chem. Int. Ed.2023, 62, e202215836) DOI: 10.1002/anie.202215836
    Selected for HOT Paper
    Selected for Back Cover Picture


    2022ACIE3.jpg
  12. Synthesis of cyclo[8]pyrrole-phosphonate complexes by anion exchange
    Hiroki Matsumoto, Naoki Matsumoto, Shigeki Mori, Ichiro Hisaki, Takahiro Nakae, Masayoshi Takase, Hidemitsu Uno, Tetsuo Okujima*
    (J. Porphyrins Phthalocyanines 2023, ) DOI: 10.1142/S1088424623500438
  1. A Proton Conductive Porous Framework of an 18-Crown-6-Ether Derivative Networked by Rigid Hydrogen Bonding Modules
    Xin Chen, Rui-Kang Huang, Kiyonori Takahashi, Shin-ichiro Noro, Takayoshi Nakamura,* Ichiro Hisaki*
    (Angew. Chem. Int. Ed. 2022, e202211686) DOI: 10.1002/anie.202211686
    Selected for Inside Cover Picture
    Selected for HOT Paper
    2022ACIE2.jpg
  2. Quinoxaline-annelated Hexadehydro[12]annulene: Use of A New Building Block to Construct a Hydrogen-bonded Hexagonal Molecular Network
    Mayu Kobayashi, Haruka Kubo, Ryusei Oketani, Ichiro Hisaki*
    (CrystEngComm, 2022, 24, 5036-5040.) DOI: 10.1039/D2CE00676F
    2022CEC.jpg
  3. Slip-Stacking of Benzothiadiazole Can Provide a Robust Structural Motif for Porous Hydrogen-bonded Organic Frameworks
    Zhuxi Yang, Akinori Saeki, Asato Inoue, Ryusei Oketani, Kazuhide Kamiya, Shuji Nakanishi, Takayoshi Nakamura,* Ichiro Hisaki*
    (Cryst. Growth Des. 2022, 22, 1172-4479.) DOI: 10.1021/acs.cgd.2c00420
    2022CGD2.jpg
  4. Geometrically Mismatched Hydrogen-bonded Framework Composed of Tetratopic Carboxylic Acid
    Zhuxi Yang, Taito Hashimoto, Ryusei Oketani, Takayoshi Nakamura,* Ichiro Hisaki*
    (Chem. Eur. J. 2022, e202201571) DOI: 10.1002/chem.202201571
    Selected for HOT Paper
    2022CEJ.jpg
  5. Order−Disorder Phase Transition between High- and Low‑Z' Crystal Structures of the P1 Space Group
    Ryusei Oketani,* Hiroki Takahashi, Simon Clevers, Akira Oyamada, Ichiro Hisaki, Gérard Coquerel, Kazuaki Yamanaka, Hirohito Tsue
    (Cryst. Growth Des. 2022, 22, 2230-2238.) DOI: 10.1021/acs.cgd.1c01330
    2022CGD1.png
  6. Robust Redox-Active Hydrogen-Bonded Organic Framework for Rechargeable Batteries
    Xiaolin Liu, Xiya Yang, Hailong Wang,* Ichiro Hisaki,* Kang Wang, Jianzhuang Jiang
    (J. Mater. Chem. A. 2022, 10, 1808-1814.) DOI: 10.1039/D1TA09194H
    2021JMCA.jpg

  7. Dianion and Dication of Tetracyclopentatetraphenylene as Decoupled Annulene-within-an-Annulene Models
    Hirokazu Miyoshi, Ryosuke Sugiura, Ryohei Kishi, Sarah N. Spisak, Zheng Wei, Atsuya Muranaka, Masanobu Uchiyama, Nagao Kobayashi, Shreyam Chatterjee, Yutaka Ie, Ichiro Hisaki,* Marina A. Petrukhina,* Tohru Nishinaga,* Masayoshi Nakano,* Yoshito Tobe*
    (Angew. Chem. Int. Ed. 2022, 61, e202115316) DOI: 10.1002/anie.202115316
    Selected for Inside Cover Picture
    Selected for VIP

    2022ACIE.jpg

  1. Two-dimensional Porous Framework Assembled through Hydrogen-bonds and Dipole-dipole Interactions
    Zhuxi Yang, Ayana Moriyama, Ryusei Oketani, Takayoshi Nakamura,* Ichiro Hisaki*
    (Chem. Lett. 2021, in press.) DOI: 10.1246/cl.210465
    2021CL.jpg
  2. Quasi Single-crystalline Transformation of Porous Frameworks Accompanied with Interlayer Rearrangements of Hydrogen Bonds
    Haruka Kubo, Ryusei Oketani, Ichiro Hisaki*
    (Chem. Commun. 2021, 57, 8568-8571.) DOI: 10.1039/D1CC03287A
    Selected for Front Cover Picture
    2021CC2.jpg
  3. A Proton Conductive Hydrogen-bonded Framework Incorporating 18-Crown-6-ether and Dicarboxy-o-terphenyl Moieties
    Xin Chen, Kiyonori Takahashi,* Kenta Kokado, Takayoshi Nakamura,* Ichiro Hisaki*
    (Mater. Adv. 2021, 2, 5639-5644.) DOI:10.1039/D1MA00411E Open Access
    Selected for Inside Front Cover Picture

    2021MA1.jpg
  4. A Hydrogen-bonded Organic Framework Based on Pyrazinopyrazine
    Qin Ji, Kiyonori Takahashi, Shin-ichiro Noro, Yusuke Ishigaki, Kenta Kokado, Takayoshi Nakamura,* Ichiro Hisaki*
    (Cryst. Growth Des. 2021, 21, 4656-4664.) DOI:10.1021/acs.cgd.1c00506
    2021CGD1.jpg
  5. Construction of Isostructural Hydrogen-bonded Organic Frameworks: Limitations and Possibilities of Pore Expansion
    Yuto Suzuki, Mario Gutiérrez, Senri Tanaka, Eduardo Gomez, Norimitsu Tohnai, Nobuhiro Yasuda, Nobuyuki Matubayasi,* Abderrazzak Douhal,* Ichiro Hisaki*
    (Chem. Sci. 2021, 12, 9563-9854.) DOI: 10.1039/D1SC02690A Open Access!
    Editor's Choice - Graeme Day
    Selected for 2021 ChemSci Pick of the Week
    Selected for 2021 Chemical Science HOT Article
    Selected for Front Cover Picture


    2021CS.jpg
  6. Crystal Structure of tetramesityl-substituted Tetracyclopenta[def,jkl,pqr,vwx]tetraphenylene
    Hirokazu Miyoshi, Ichiro Hisaki,* Yoshito Tobe*
    (Eur. J. Org. Chem. 2021, 3528-3534.) DOI:10.1002/ejoc.202100503
    2021EJOC.jpg
  7. Fluorescent Molecular Glass Based on Hexadehydrotribenzo[12]annulene
    Yotaro Kasahara, Ichiro Hisaki, Tomoyuki Akutagawa, Takashi Takeda*
    (Chem. Commun. 2021, 57, 5349-5472.) DOI:10.1039/D1CC01356D
  8. Synthesis and Photobehavior of a NewDehydrobenzoannulene-Based HOF with Fluorine Atoms: From Solution to Single Crystals Observation
    Eduardo Gomez, Ichiro Hisaki,* Abderrazzak Douhal*
    (Int. J. Mol. Sci. 2021, 22, 4803.) DOI: 10.3390/ijms22094803
    2021IJMS1.jpg
  9. Deciphering the Behavior of a New MOF and Its Composites Under Light at Ensemble and Single Crystal Levels: Relevance to its Photonic Applications
    Eduardo Gomez, Daisuke Yasumiya, Norimitsu Tohnai, Miquel Moreno, Boiko Cohen,* Ichiro Hisaki,* Abderrazzak Douhal*
    (J. Mater. Chem. C 2021, 9, 6418-6435.) DOI:10.1039/D1TC01104A
    Selected for Inside Cover Picture
    2021JMCC1.jpg
  10. Molecular Motion of Halogenated Ethylammonium/[18]crown-6 Supramolecular Ions in Nickel Dithiolate Magnetic Crystals
    Naohiro Hasuo, Kiyonori Takahashi,* Ichiro Hisaki, Kenta Kokado, Takayoshi Nakamura,*
    (CrystEngComm 2021, 23, 2756-2763.) DOI: 10.1039/D1CE00253H
  11. Redox-induced Reversible [2+2] Cycloaddition of An Ethenofused Diporphyrin
    Kazuya Miyagawa, Ichiro Hisaki, Norihito Fukui, Hiroshi Shinokubo*
    (Chem. Sci. 2021, 12, 5224-5229.) DOI:10.1039/d1sc00438g
  12. Hydrogen-bonded Organic Framework Based on Redox-active Tri(dithiolylidene)cyclohexanetrione
    Kilingaru I. Shivakumar, Shin-ichiro Noro, Yuna Yamaguchi, Yusuke Ishigaki, Akinori Saeki, Kiyonori Takahashi, Takayoshi Nakamura,* Ichiro Hisaki*
    (Chem. Commun. 2021, 57, 1157-1160.) DOI: 10.1039/D0CC07776C
    2021CC1.jpg
  13. A Series of Bisamide‐substituted Diacetylenes Exhibiting Terminal Alkyl Odd‐even Parity Effect on Mechano‐activation for the Subsequent Photopolymerization Property
    Jiajun Qi, Yuna Kim, Kiyonori Takahashi, Ken'ichi Aoki, Ichiro Hisaki, Takayoshi Nakamura, Nobuyuki Tamaoki*
    (Chem. Eur. J. 2021, 27, 3832-3841.) DOI: 10.1002/chem.202004768

  1. HOFs Under Light: Relevance to Photon-Based Science and Applications
    Maria Rosariadi Nunzio, Ichiro Hisaki, Abderrazzak Douhal
    J. Photochem. Photobio. C: Photochem. Rev. 2021, 47, 100418.
    DOI: 10.1016/j.jphotochemrev.2021.100418
  2. Structural Characterization of acid-responsive hydrogen-bonded organic frameworks with permanent porosity
    Ichiro Hisaki,* Yuto Suzuki
    SPring-8/SACLA Research Frontiers 2020, 2021, Aug. 84-85.
    (PDF file)

  1. Hydrogen-bonded Organic Frameworks of Twisted Polycyclic Aromatic Hydrocarbon
    Yuto Suzuki, Norimitsu Tohnai, Akinori Saeki, Ichiro Hisaki*
    (Chem. Commun. 2020, 56, 13369-13372)
    2020CC1.jpg
  2. An Europium(III) Luminophore with Pressure-sensing Units: Effective Back Energy Transfer in Coordination Polymers with Hexadentate Porous Stable Networks
    Yasuchika Hasegawa,* Takuya Sawanobori, Yuichi Kitagawa, Sunao Shoji, Koji Fushimi, Yuta Nakasaka, Takao Masuda, Ichiro Hisaki
    (ChemPlusChem 2020, 85, 1989-1993.) DOI: 10.1002/cplu.202000513
  3. Triaxially-woven Hydrogen-bonded Chicken Wires of Tetrakis(carboxybiphenyl)ethene Derivative
    Yuto Suzuki, Norimitsu Tohnai, Ichiro Hisaki*
    (Chem. Eur. J. 2020, 26, 17056-17062.) DOI: 10.1002/chem.202002546 Cover Feature
    CEJ20200623.gif
  4. Positional Effects of Annelated Pyrazine Rings on Structure and Stability of Hydrogen-bonded Frameworks of Hexaazatrinaphthylene Derivatives
    Ichiro Hisaki,* Qin Ji, Kiyonori Takahashi, Norimitsu Tohnai, Takayoshi Nakamura
    (Cryst. Growth Des. 2020, 20, 3190-3198.) DOI: 10.1021/acs.cgd.0c00055
    cgd2020-1.gif
  5. Shape-Persistent Phenylene-Ethynylene Macrocycles Spectroscopy and Dynamics: From Molecules to the Hydrogen-Bonded Organic Framework Material
    Eduardo Gomez, Maria Rosaria di Nunzio, Miquel Moreno, Ichiro, Hisaki,* Abderrazzak Douhal*
    (J. Phys. Chem. C 2020, 124, 6938-6951.) DOI: 10.1021/acs.jpcc.0c01369
    jpcc20206938.gif
  1. 多孔性分子結晶の動向と展望
    久木一朗
    日本結晶学会誌, 2020, 受理
  2. 水素結合で組み立てる多孔質分子結晶
    久木一朗
    高分子, 2020, 69, 396-397.
  3. 多孔性と光機能性とをあわせもつ複合機能性の水素結合性有機フレームワークの構築を目指して
    久木一朗
    光化学, 2020, 51, 36-39.
  4. Hydrogen-bonded porous frameworks constructed by rigid π-conjugated molecules with carboxy groups
    Ichiro Hisaki
    J. Incl. Phenom. Macro. Chem. 2020, 96, 215-231. (Open Access!)
    DOI: 10.1007/s10847-019-00972-0
  1. Layered Hydrogen-bonded Organic Frameworks as Highly Crystalline Porous Materials
    Ichiro Hisaki, Qin Ji, Kiyonori Takahashi, Takayoshi Nakamura
    In Advances in Organic Crystal Chemistry -Comprehensive Reviews 2020,
    Eds. M. Sakamoto and H. Uekusa, Springer, 2020, chapter 11, 199-220.
  1. Ichiro Hisaki,* Xin Chen, Kiyonori Takahashi, Takayoshi Nakamura,
    "Designing Hydrogen-bonded Organic Frameworks (HOFs) with Permanent Porosity"
    (Angew. Chem. Int. Ed. 2019, 58, 11160-11170.) DOI:10.1002/anie.201902147(Minireview)

  2. 久木一朗, 高橋仁徳, 中村貴義
    "カルボン酸の水素結合で組み上げた多孔質有機フレームワーク"
    (有機合成化学協会誌 2019, 77, 706-715.) DOI:10.5059/yukigoseikyokaishi.77.706

  3. 久木一朗, 中村貴義
    "弱い結合で強固な機能空間をつくる-水素結合を用いた分子多孔質材料創出への挑戦"
    (化学 2019, 74, 68-69.)

  4. 久木一朗
    "水素結合で組み上げた多孔性二次元シートの積層構造"
    (日本結晶学会誌 2016, 58, 209-214.) 10.5940/jcrsj.58.209

  5. 久木一朗
    "有機結晶のデザイン―分子を整列させるには?―"
    (化学と教育 2015, 63, 372-375.) DOI:10.20665/kakyoshi.63.8_372

  6. Ichiro Hisaki*, Toshiyuki Sasaki, Norimitsu Tohnai, Mikiji Miyata* "Supramolecular-Tilt-Chirality on Two-Fold Helical Assemblies"
    (Chem. Eur. J. 2012, 18, 10066-10073) Concept, Selected for Frontispiece

  7. Ichiro Hisaki,* Norimitsu Tohnai, Mikiji Miyata* "Supramolecular Tilt Chirality in Crystals of Steroids and Alkaloids" (Review for Nina Berova Special Issue)
    (Chirality 2008, 20, 330-336.)

  8. Mikiji Miyata,* Norimitsu Tohnai, Ichiro Hisaki, "Supramolecular Chirality in Crystalline Assemblies of Bile Acids and Their Derivatives; Three-Axial, Tilt, Helical, and Bundle Chirality"
    (Molecules 2007, 12, 1973-2000.)

  9. Mikiji Miyata,* Norimitsu Tohnai, Ichiro Hisaki, "Crystalline Host-guest Assemblies of Steroidal and Related Molecules: Diversity, Hierarchy and Supramolecular Chirality"
    (Acc. Chem. Res. 2007, 40, 694-702.)

  10. Ichiro Hisaki, Motohiro Sonoda, Yoshito Tobe,* "Strained Dehydrobenzoannulenes"
    ( Eur. J. Org. Chem. 2006, 833-847.) (Micro Review)