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- Synthesis, Solid State Structures, and Properties of Linear and Tripodal Flexible Molecules with Pyrazinopyrazine Moieties
Yuto Ohmura, Ryusei Oketani, Akihito Konishi, Makoto Yasuda, Ichiro Hisaki*
(Chem. Lett. 2024, 53, upae140) DOI: 10.1093/chemle/upae140
- Crystallization-Induced Diastereomeric Transformation of Chiral Ozanimod Key Intermediate Using Homogeneous
Ryusei Oketani,* Koki Shiohara, Ichiro Hisaki*
(Cryst. Growth Des. 2024, 24, 5397-5401.) DOI: 10.1021/acs.cgd.4c00604
- Transition Behaviors of Isostructural Hydrogen-Bonded Frameworks Composed of Naphthalene, Quinoxaline, and Pyrazinopyrazine Derivatives
Haruka Kubo, Shunsuke Konishi, Ryusei Oketani, Takashi Hayashi, Ichiro Hisaki*
(Chem. Eur. J. 2024, 30, e202401645) DOI: 10.1002/chem.202401645 Open Access!
Selected for Hot paper
Selected for Inside Cover Picture
- Unravelling the Photobehavior of 2,1,3-Benzothiadiazole-based HOF and its Molecular Units: Experimental and Theoretical Insights into their Spectroscopic Properties in Solutions and Solid State
Mario de la Hoz Tomás, Juan Ángel Organero, Maria Rosaria di Nunzio, Taito Hashimoto, Ichiro Hisaki, Abderrazzak Douhal*
(J. Mater. Chem. C 2024, 12, 9112-9129.) DOI: 10.1039/D4TC01368A
Selected for Front Cover Picture
- Semicontinuous Temperature Cycle-Induced Deracemization Using an Axially Chiral Naphthamide
Ryusei Oketani,* Riku Naito, Ichiro Hisaki*
(Org. Process Res. Dev. 2024, 28, 3570-3577.) DOI: 10.1021/acs.oprd.4c00091
Selected for Front Cover Picture
- Photo-responsive Hydrogen-Bonded Molecular Networks Capable of Retaining Crystalline Periodicity after Isomerization
Koki Kasuya, Ryusei Oketani, Souta Matsuda, Hiroyasu Sato, Fumitaka Ishiwari, Akinori Saeki, Ichiro Hisaki*
(Angew. Chem. Int. Ed. 2024, e202404700.) DOI: 10.1002/anie.202404700 Open Access!
- A Hydrogen-Bonded, Hexagonally-Networked, Layered Framework with Large Aperture Designed by Structural Synchronization of a Macrocycle and Supramolecular Synthon
Hiroki Yoshimura, Ryusei Oketani, Miki Naruoka, Norimitsu Tohnai, Ichiro Hisaki*
(Precis. Chem. 2024, 2, 221-228.) DOI: 10.1021/prechem.4c00019 Open Access!
Selected for Front Cover Picture
- Thermal fluctuation-induced selective CO2 uptake of seemingly nonporous N,C-protected dipeptide crystals as elucidated by in situ X-ray crystallographic analysis
Kazuaki Yamanaka, Ryusei Oketani, Yuya Mori, Takashi Sato, Seiji Tsuzuki, Hiroki Takahashi, Hirohito Tsue*
(CrystEngComm 2024, 26, 2314-2321.) DOI: 10.1039/D3CE01018J
- An Expanded Hydrogen-bonded Organic Framework Formed by A Tetrakis(terphenyl)ethene Derivative
Mao Yamaguchi, Mario de la Hoz Tomás, Ayano Fujiwara, Ryusei Oketani, Kohei Okubo, Kouki Oka, Norimitsu Tohnai, Abderrazzak Douhal,* Ichiro Hisaki*
(Bull. Chem. Soc. J. 2024, 97, uoae004) DOI: 10.1093/bulcsj/uoae004
Selected Paper
Selected for Inside Cover Picture
- キラル化合物の融点相図の作成と結晶化による光学分割への適応
桶谷龍成, 久木一朗
(熱測定 2024, 51, 78-84.)
- Structural Details of Carboxylic Acid-based Hydrogen-bonded Organic Frameworks (HOFs)
Yuto Suzuki, Ichiro Hisaki*
(Polym. J. 2024, 56, 1-16.) DOI:10.1038/s41428-023-00840-2 Open Access!
Selected for Cover Picture
- Influence of core size on self-assembled molecular networks composed of C3h-symmetric building blocks through hydrogen bonding interactions: structural features and chirality
Matsuhiro Maeda, Kotoka Oda, Ichiro Hisaki, Kazukuni Tahara*
(RSC Adv. 2023, 13, 29512-29521.) DOI: 10.1039/D3RA05762C
- Synthesis and Characterization of Dibenzothieno[a,f]pentalenes Enabling Large Antiaromaticity and Moderate Open-shell Character Through a Small Energy Barrier for Bond-shift Valence Tautomerization
Yusuke, Mizuno, Akira Nogata, Mitsuharu Suzuki, Ken-ichi Nakayama, Ichiro Hisaki, Ryohei Kishi, Akihito Konishi,* Makoto Yasuda*
(J. Am. Chem. Soc. 2023, 145, 20595-20609.) DOI: 10.1021/jacs.3c07356
- Photocyclization Reaction and Related Photodynamics in the Photoproducts of a Tetraphenylethylene Derivative with Bulky Substituents: Unexpected Solvent Viscosity Effect
Mario de la Hoz Tomás, Mao Yamaguchi, Boiko Cohen, Ichiro Hisaki, Abderrazzak Douhal*
(Phys. Chem. Chem. Phys. 2023, 25, 18874-18888.) DOI:10.1039/D3CP01295F
- Statically and Dynamically Flexible Hydrogen-bonded Frameworks Based on 4,5,9,10-Tetrakis(4-carboxyphenyl)pyrene
Taito Hashimoto, Ryusei Oketani, Asato Inoue, Kohei Okubo, Kouki Oka, Norimitsu Tohnai, Kazuhide Kamiya, Shuji Nakanishi, Ichiro Hisaki*
(Chem. Commun. 2023, 59, 7224-7227.) DOI: 10.1039/D3CC01877F Open access!
- Construction of Hydrogen-bonded Crystalline Frameworks Using Tetrakis(carboxyphenyl)dimethyl-dihydropyrene Derivative
Yuna Yamaguchi, Kouki Kasuya, Ryusei Oketani, Ichiro Hisaki*
(Chem. Lett. 2023, 52, 542-545.) DOI: 10.1246/cl.230198
- Overcoming a Solid Solution System on Chiral Resolution: Combining Crystallization and Enantioselective Dissolution
Ryusei Oketani,* Koki Shiohara, Ichiro Hisaki*
(Chem. Commun. 2023, 59, 6175-6178.) DOI: 10.1039/D3CC01352A Open access!
Selected for Inside Cover Picture
- s-Indacene Revisited: Modular Synthesis and Modulation of Structures and Molecular Orbitals of Hexaaryl Derivatives
Shun-Jie Jhang, Jayabalan Pandidurai, Ching-Piao Chu, Hirokazu Miyoshi, Yuta Takahara, Masahito Miki, Hikaru Sotome, Hiroshi Miyasaka, Shreyam Chatterjee, Rumi Ozawa, Yutaka Ie, Ichiro Hisaki, Chia-Lin Tsai, Yen-Ju Cheng,* Yoshito Tobe*
(J. Am. Chem. Soc. 2023, 145, 4716-4729.) DOI: 10.1021/jacs.2c13159
- Uniaxial Negative Thermal Expansion Induced by Molecular Rotation in One-Dimensional Supramolecular Assembly with Associated Peculiar Magnetic Behavior
Kiyonori Takahashi,* Yuki Shirakawa, Hiroki Sakai, Ichiro Hisaki, Shin-ichiro Noro, Tomoyuki Akutagawa, Motohiro Nakano, Takayoshi Nakamura*
(J. Mater. Chem. C 2023, 11, 1891-1898.) DOI: 10.1039/D2TC04874D
- Deciphering the Ultrafast Dynamics of a New Tetraphenylethylene Derivative in Solutions: Charge Separation, Phenyl Rings Rotation and C=C Bond Twisting
Mario de la Hoz Tomás, Mao Yamaguchi, Boiko Cohen,* Ichiro Hisaki,* Abderrazzak Douhal*
(Phys. Chem. Chem. Phys. 2023, 25, 1755-1767.) DOI: 10.1039/D2CP05220B
Selected for 2023 PCCP HOT articles
- Isomeric Effect of Naphthyl Spacers on Structures and Properties of Isostructural Porous Crystalline Frameworks
Yuto Suzuki, Mao Yamaguchi, Ryusei Oketani, Ichiro Hisaki*
(Mater. Chem. Front. 2023, 7, 106-116.) DOI: 10.1039/D2QM01091G
Selected for 2022 Materials Chemistry Frontiers HOT articles
- Single Crystalline, Non-stoichiometric Cocrystals of Hydrogen-Bonded Organic Frameworks
Taito Hashimoto, Ryusei Oketani, Masaki Nobuoka, Shu Seki, Ichiro Hisaki*
(Angew. Chem. Int. Ed. 2023, 62, e202215836) DOI: 10.1002/anie.202215836
Selected for HOT Paper
Selected for Back Cover Picture
- Synthesis of cyclo[8]pyrrole-phosphonate complexes by anion exchange
Hiroki Matsumoto, Naoki Matsumoto, Shigeki Mori, Ichiro Hisaki, Takahiro Nakae, Masayoshi Takase, Hidemitsu Uno, Tetsuo Okujima*
(J. Porphyrins Phthalocyanines 2023 ) DOI: 10.1142/S1088424623500438
- コングロメレートとの固溶体形成によるラセミ化合物のデラセミ化
桶谷龍成、黒田玲子、Clement Pinetre, Francois-Xavier Gendron, Christian Aupetit, Thierry Buffeteau, Gerard Coquerel
有機結晶部会ニュースレター, 2023, 56, 3-4.
- 結晶化とエナンチオ選択的な溶解を組み合わせた固溶体の光学分割
塩原康希、桶谷龍成、久木一朗
有機結晶部会ニュースレター, 2023, 55, 7-8.
- ピレンを基盤とする静的・動的に柔軟な水素結合性フレームワーク
橋本泰利、桶谷龍成、 久木一朗
有機結晶部会ニュースレター, 2023, 55, 9-10.
- ピレン/ヒドロピレンを基盤とした非化学量論的組成の水素結合性フレームワーク
橋本泰利、桶谷龍成、 久木一朗
有機結晶部会ニュースレター, 2023, 54, 6-7.
- A Proton Conductive Porous Framework of an 18-Crown-6-Ether Derivative Networked by Rigid Hydrogen Bonding Modules
Xin Chen, Rui-Kang Huang, Kiyonori Takahashi, Shin-ichiro Noro, Takayoshi Nakamura,* Ichiro Hisaki*
(Angew. Chem. Int. Ed. 2022, 61, e202211686) DOI: 10.1002/anie.202211686
Selected for HOT Paper
Selected for Inside Cover Picture
- Quinoxaline-annelated Hexadehydro[12]annulene: Use of A New Building Block to Construct a Hydrogen-bonded Hexagonal Molecular Network
Mayu Kobayashi, Haruka Kubo, Ryusei Oketani, Ichiro Hisaki*
(CrystEngComm, 2022, 24, 5036-5040.) DOI: 10.1039/D2CE00676F
- Slip-Stacking of Benzothiadiazole Can Provide a Robust Structural Motif for Porous Hydrogen-bonded Organic Frameworks
Zhuxi Yang, Akinori Saeki, Asato Inoue, Ryusei Oketani, Kazuhide Kamiya, Shuji Nakanishi, Takayoshi Nakamura,* Ichiro Hisaki*
(Cryst. Growth Des. 2022, 22, 4472-4479.) DOI: 10.1021/acs.cgd.2c00420
- Geometrically Mismatched Hydrogen-bonded Framework Composed of Tetratopic Carboxylic Acid
Zhuxi Yang, Taito Hashimoto, Ryusei Oketani, Takayoshi Nakamura,* Ichiro Hisaki*
(Chem. Eur. J. 2022, 28, e202201571) DOI: 10.1002/chem.202201571
Selected for HOT Paper
- Order−Disorder Phase Transition between High- and Low‑Z' Crystal Structures of the P1 Space Group
Ryusei Oketani,* Hiroki Takahashi, Simon Clevers, Akira Oyamada, Ichiro Hisaki, Gérard Coquerel, Kazuaki Yamanaka, Hirohito Tsue
(Cryst. Growth Des. 2022, 22, 2230-2238.) DOI: 10.1021/acs.cgd.1c01330
- Robust Redox-Active Hydrogen-Bonded Organic Framework for Rechargeable Batteries
Xiaolin Liu, Xiya Yang, Hailong Wang,* Ichiro Hisaki,* Kang Wang, Jianzhuang Jiang
(J. Mater. Chem. A. 2022, 10, 1808-1814.) DOI: 10.1039/D1TA09194H
- Dianion and Dication of Tetracyclopentatetraphenylene as Decoupled Annulene-within-an-Annulene Models
Hirokazu Miyoshi, Ryosuke Sugiura, Ryohei Kishi, Sarah N. Spisak, Zheng Wei, Atsuya Muranaka, Masanobu Uchiyama, Nagao Kobayashi, Shreyam Chatterjee, Yutaka Ie, Ichiro Hisaki,* Marina A. Petrukhina,* Tohru Nishinaga,* Masayoshi Nakano,* Yoshito Tobe*
(Angew. Chem. Int. Ed. 2022, 61, e202115316) DOI: 10.1002/anie.202115316
Selected for Inside Cover Picture
Selected for VIP
- 水素結合で分子をつなげた多孔質構造体の構造・機能設計
久木一朗
有機分子・バイオエレクトロニクス分科会会誌, 2022, 33, 20-25.
- 水素結合の指向性を利用した多孔性分子結晶のデザイン
久木一朗
生産と技術, 2022, 47, 85-88.
- HOFs Built from Hexatopic Carboxylic Acids: Structure, Porosity, Stability, and Photophysics
Maria Rosariadi Nunzio, Yuto Suzuki, Ichiro Hisaki,* Abderrazzak Douhal*
Int. J. Mol. Sci. 2022, 23, 1929.
DOI: 10.3390/ijms23041929 Open Access!
- 水素結合の組み換えをともなう有機多孔質構造体の単結晶構造相転移
久保遥、桶谷龍成、 久木一朗
有機結晶部会ニュースレター, 2022, 50, 8-9.
- Two-dimensional Porous Framework Assembled through Hydrogen-bonds and Dipole-dipole Interactions
Zhuxi Yang, Ayana Moriyama, Ryusei Oketani, Takayoshi Nakamura,* Ichiro Hisaki*
(Chem. Lett. 2021, 50, 1909-1912.) DOI: 10.1246/cl.210465
- Quasi Single-crystalline Transformation of Porous Frameworks Accompanied with Interlayer Rearrangements of Hydrogen Bonds
Haruka Kubo, Ryusei Oketani, and Ichiro Hisaki*
(Chem. Commun. 2021, 57, 8568-8571.) DOI: 10.1039/D1CC03287A
Selected for Front Cover Picture
- A Proton Conductive Hydrogen-bonded Framework Incorporating 18-Crown-6-ether and Dicarboxy-o-terphenyl Moieties
Xin Chen, Kiyonori Takahashi,* Kenta Kokado, Takayoshi Nakamura,* Ichiro Hisaki*
(Mater. Adv. 2021, 2, 5639-5644.) DOI: 10.1039/D1MA00411E Open Access!
Selected for Inside Front Cover Picture
- A Hydrogen-bonded Organic Framework Based on Pyrazinopyrazine
Qin Ji, Kiyonori Takahashi, Shin-ichiro Noro, Yusuke Ishigaki, Kenta Kokado, Takayoshi Nakamura,* Ichiro Hisaki*
(Cryst. Growth Des. 2021, 21, 4656-4664.) DOI:10.1021/acs.cgd.1c00506
- Construction of Isostructural Hydrogen-bonded Organic Frameworks: Limitations and Possibilities of Pore Expansion
Yuto Suzuki, Mario Gutiérrez, Senri Tanaka, Eduardo Gomez, Norimitsu Tohnai, Nobuhiro Yasuda, Nobuyuki Matubayasi,* Abderrazzak Douhal,* Ichiro Hisaki*
(Chem. Sci. 2021, 12, 9607-9618.) DOI: 10.1039/D1SC02690A Open Access!
Editor's Choice - Graeme Day
Selected for 2021 ChemSci Pick of the Week
Selected for 2021 Chemical Science HOT Article
Selected for Front Cover Picture
- Crystal Structure of tetramesityl-substituted Tetracyclopenta[def,jkl,pqr,vwx]tetraphenylene
Hirokazu Miyoshi, Ichiro Hisaki,* Yoshito Tobe*
(Eur. J. Org. Chem. 2021, 3528-3534.) DOI:10.1002/ejoc.202100503
- Fluorescent Molecular Glass Based on Hexadehydrotribenzo[12]annulene
Yotaro Kasahara, Ichiro Hisaki, Tomoyuki Akutagawa, Takashi Takeda*
(Chem. Commun. 2021, 57, 5349-5472.) DOI:10.1039/D1CC01356D
- Synthesis and Photobehavior of a NewDehydrobenzoannulene-Based HOF with Fluorine Atoms: From Solution to Single Crystals Observation
Eduardo Gomez, Ichiro Hisaki,* Abderrazzak Douhal*
(Int. J. Mol. Sci. 2021, 22, 4803.) DOI: 10.3390/ijms22094803 Open Access!
- Deciphering the Behavior of a New MOF and Its Composites Under Light at Ensemble and Single Crystal Levels: Relevance to its Photonic Applications
Eduardo Gomez, Daisuke Yasumiya, Norimitsu Tohnai, Miquel Moreno, Boiko Cohen,* Ichiro Hisaki,* Abderrazzak Douhal*
(J. Mater. Chem. C 2021, 9, 6418-6435.) DOI:10.1039/D1TC01104A
Selected for Inside Cover Picture
- Molecular Motion of Halogenated Ethylammonium/[18]crown-6 Supramolecular Ions in Nickel Dithiolate Magnetic Crystals
Naohiro Hasuo, Kiyonori Takahashi,* Ichiro Hisaki, Kenta Kokado, Takayoshi Nakamura,*
(CrystEngComm 2021, 23, 2756-2763.) DOI: 10.1039/D1CE00253H
- Redox-induced Reversible [2+2] Cycloaddition of An Ethenofused Diporphyrin
Kazuya Miyagawa, Ichiro Hisaki, Norihito Fukui, Hiroshi Shinokubo*
(Chem. Sci. 2021, 12, 5224-5229.) DOI:10.1039/d1sc00438g
- Hydrogen-bonded Organic Framework Based on Redox-active Tri(dithiolylidene)cyclohexanetrione
Kilingaru I. Shivakumar, Shin-ichiro Noro, Yuna Yamaguchi, Yusuke Ishigaki, Akinori Saeki, Kiyonori Takahashi, Takayoshi Nakamura,* Ichiro Hisaki,*
(Chem. Commun. 2021, 57, 1157-1160.) DOI: 10.1039/D0CC07776C
- A Series of Bisamide‐substituted Diacetylenes Exhibiting Terminal Alkyl Odd‐even Parity Effect on Mechano‐activation for the Subsequent Photopolymerization Property
Jiajun Qi, Yuna Kim, Kiyonori Takahashi, Ken'ichi Aoki, Ichiro Hisaki, Takayoshi Nakamura, Nobuyuki Tamaoki,*
(Chem. Eur. J. 2021, 27, 3832-3841.) DOI: 10.1002/chem.202004768
- HOFs Under Light: Relevance to Photon-Based Science and Applications
Maria Rosariadi Nunzio, Ichiro Hisaki, Abderrazzak Douhal*
J. Photochem. Photobio. C: Photochem. Rev. 2021, 47, 100418.
DOI: 10.1016/j.jphotochemrev.2021.100418
- Structural Characterization of acid-responsive hydrogen-bonded organic frameworks with permanent porosity
Ichiro Hisaki,* Yuto Suzuki
SPring-8/SACLA Research Frontiers 2020, 2021, Aug. 84-85.
(PDF file)
- HAT誘導体による一連の同型構造構築:空孔拡張の限界と可能性
鈴木悠斗, 久木一朗
有機結晶部会ニュースレター, 2021, 49, 5-6.
- 多孔性分子結晶の動向と展望
久木一朗
日本結晶学会誌, 2020, 62, 133-134.
- 水素結合で組み立てる多孔質分子結晶
久木一朗
高分子, 2020, 69, 396-397.
- 多孔性と光機能性とをあわせもつ複合機能性の水素結合性有機フレームワークの構築を目指して
久木一朗
光化学, 2020, 51, 36-39.
- Hydrogen-bonded porous frameworks constructed by rigid π-conjugated molecules with carboxy groups
Ichiro Hisaki
J. Incl. Phenom. Macro. Chem. 2020, 96, 215-231. (Open Access!)
DOI: 10.1007/s10847-019-00972-0
- Layered Hydrogen-bonded Organic Frameworks as Highly Crystalline Porous Materials
Ichiro Hisaki, Qin Ji, Kiyonori Takahashi, Takayoshi Nakamura
In Advances in Organic Crystal Chemistry -Comprehensive Reviews 2020, Eds. M. Sakamoto and H. Uekusa, Springer, 2020, chapter 11, 199-220.
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Ichiro Hisaki,* Xin Chen, Kiyonori Takahashi, Takayoshi Nakamura,
"Designing Hydrogen-bonded Organic Frameworks (HOFs) with Permanent Porosity"
(Angew. Chem. Int. Ed. 2019,
58, 11160-11170.)
DOI:10.1002/anie.201902147(Minireview)
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久木一朗, 高橋仁徳, 中村貴義
"カルボン酸の水素結合で組み上げた多孔質有機フレームワーク"
(有機合成化学協会誌 2019,
77, 706-715.)
DOI:10.5059/yukigoseikyokaishi.77.706
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久木一朗, 中村貴義
"弱い結合で強固な機能空間をつくる-水素結合を用いた分子多孔質材料創出への挑戦"
(化学 2019,
74, 68-69.)
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久木一朗
"水素結合で組み上げた多孔性二次元シートの積層構造"
(日本結晶学会誌 2016,
58, 209-214.)
10.5940/jcrsj.58.209
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久木一朗
"有機結晶のデザイン―分子を整列させるには?―"
(化学と教育 2015,
63, 372-375.)
DOI:10.20665/kakyoshi.63.8_372
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Ichiro Hisaki*, Toshiyuki Sasaki, Norimitsu Tohnai, Mikiji Miyata*
"Supramolecular-Tilt-Chirality on Two-Fold Helical Assemblies"
(Chem. Eur. J. 2012, 18, 10066-10073) Concept, Selected for Frontispiece
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Ichiro Hisaki,* Norimitsu Tohnai, Mikiji Miyata* "Supramolecular Tilt
Chirality in Crystals of Steroids and Alkaloids" (Review for Nina
Berova Special Issue)
(Chirality 2008, 20, 330-336.)
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Mikiji Miyata,* Norimitsu Tohnai, Ichiro Hisaki, "Supramolecular
Chirality in Crystalline Assemblies of Bile Acids and Their
Derivatives; Three-Axial, Tilt, Helical, and Bundle Chirality"
(Molecules 2007, 12, 1973-2000.)
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Mikiji Miyata,* Norimitsu Tohnai, Ichiro Hisaki, "Crystalline
Host-guest Assemblies of Steroidal and Related Molecules: Diversity,
Hierarchy and Supramolecular Chirality"
(Acc. Chem. Res. 2007, 40, 694-702.)
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Ichiro Hisaki, Motohiro Sonoda, Yoshito Tobe,* "Strained Dehydrobenzoannulenes"
( Eur. J. Org. Chem. 2006, 833-847.) (Micro Review)