NEW! Yohei Hattori,* Ryota Matsuoka,* Atsumi Baba, Shun Yoshida, Mihoko Yamada, Ryo Fujita, Daiya Suzuki, Yoshitane Imai, Kingo Uchida, Tetsuro Kusamoto, Gwénaël Rapenne, Tsuyoshi Kawai*
"A Luminescent Stable Triarylmethyl Diradical with an Axially Chiral Spacer" Chem. Eur. J. in press. DOI:10.1002/chem.202500284 → link
2024
Takuto Mibu,* Ryota Matsuoka, Masanari Nagasaka, and Tetsuro Kusamoto*
"Emission enhancement in a luminescent polychlorinated diphenylpyridylmethyl radical through coordination to silver(I)" Dalton. Trans.2024, 54, 2265-2270. → link
Takuya Akiyama, Tetsuro Kusamoto, Kazushi Mashima, and Hayato Tsurugi*
"Synthesis of Multisubstituted Cyclopentadiene Derivatives from 3,3-Disubstituted Cyclopropenes and Internal Alkynes Catalyzed by Low-Valent Niobium Complexes" J. Am. Chem. Soc.2024, 146, 33338-33348. → link
Sota Tamaki, Tetsuro Kusamoto, and Hayato Tsurugi*
"Decarboxylative Alkylation of Carboxylic Acids with Easily Oxidizable Functional Groups Catalyzed by an Imidazole-Coordinated Fe3 Cluster under Visible Light Irradiation" Chem. Eur. J.2024, 30, e202402705. → link
Asato Mizuno,* Ryota Matsuoka, Shojiro Kimura, Keisuke Ochiai, and Tetsuro Kusamoto*
"Spin-Correlated Luminescence of a Carbazole-Containing Diradical Emitter: Single-Molecule Magnetoluminescence and Thermally Activated Emission" J. Am. Chem. Soc.2024, 146, 18470-18483. → link
Asato Mizuno, Ryota Matsuoka, Takuto Mibu, and Tetsuro Kusamoto*
"Luminescent Radicals" Chem. Rev.2024, 124, 1034-1121. → link
2023
Ryota Matsuoka,* Shojiro Kimura, Tomoaki Miura, Tadaaki Ikoma, and Tetsuro Kusamoto*
"Single-molecule Magnetoluminescence from a Spatially Confined Persistent Diradical Emitter" J. Am. Chem. Soc.2023, 145, 13615-13622. → link
Yugo Oshima,* Taishi Takenobu, Jiang Pu, Keisuke Ishiguro, Reizo Kato, Hiroshi M. Yamamoto, and Tetsuro Kusamoto
"A Memristive Oscillator" Adv. Physics Res.2023, 2300117. → link
Yohei Hattori,* Ryota Kitajima, Atsumi Baba, Kohei Yamamoto, Ryota Matsuoka, Tetsuro Kusamoto, and Kingo Uchida
"Effects of hydrocarbon substituents on highly fluorescent bis(4-phenylphenyl)pyridylmethyl radical derivatives" Mater. Adv.2023, 4, 5149-5159. → link
2022
Hwan-Hee Cho, Shun Kimura, Neil C. Greenham, Yuki Tani, Ryota Matsuoka, Hiroshi Nishihara, Richard H. Friend,* Tetsuro Kusamoto,* and Emrys W. Evans*
"Near-Infrared Light-Emitting Diodes from Organic Radicals with Charge Control" Adv. Opt. Mater.2022, 10, 2200628. → link
Ryota Matsuoka, Asato Mizuno, Takuto Mibu, and Tetsuro Kusamoto*
"Luminescence of doublet molecular systems" Coord. Chem. Rev.2022, 467, 214616. → link
Taro Suemune, Keita Sonoda, Shuichi Suzuki, Hiroyasu Sato, Tetsuro Kusamoto, and Akira Ueda*
"Partially Oxidized Purely Organic Zwitterionic Neutral Radical Conductor: Multi-step Phase Transitions and Crossover Caused by Intra- and Intermolecular Electronic Interactions" J. Am. Chem. Soc.2022, in press. DOI: 10.1021/jacs.2c08813 → link
Yohei Hattori,* Ryota Kitajima, Wataru Ota, Ryota Matsuoka, Tetsuro Kusamoto, Tohru Sato, and Kingo Uchida
"The simplest structure of a stable radical showing high fluorescence efficiency in solution: benzene donors with triarylmethyl radicals" Chem. Sci.2022, 13, 13418-13425. → link
Yohei Hattori,* Ryota Kitajima, Ryota Matsuoka, Tetsuro Kusamoto, Hiroshi Nishihara, and Kingo Uchida
"Amplification of luminescence of stable radicals by coordination to NHC-gold(I) complex" Chem. Commun.2022, 58, 2560-2563. → link
2021
Ryota Matsuoka, Tatsuhiro Yoshimoto, Yasutaka Kitagawa, and Tetsuro Kusamoto*
"Structural and Magnetic Studies on Nickel(II) and Cobalt(II) Complexes with Polychlorinated Diphenyl(4-pyridyl)methyl Radical Ligands" Molecules2021, 26, 5596. → link
Tetsuro Kusamoto* and Shun Kimura
"Photostable Luminescent Triarylmethyl Radicals and Their Metal Complexes: Photofunctions Unique to Open-shell Electronic States" Chem. Lett.2021, 50, 1445-1459. OPEN ACCESS → link
Ryota Matsuoka,* Shojiro Kimura, and Tetsuro Kusamoto*
"Solid-State Room-Temperature Near-Infrared Photoluminescence of a Stable Organic Radical" ChemPhotoChem2021, 5, 669-673. → link
Shun Kimura, Ryota Matsuoka, Shojiro Kimura, Hiroshi Nishihara, and Tetsuro Kusamoto*
"Radical-Based Coordination Polymers as a Platform for Magnetoluminescence" J. Am. Chem. Soc.2021, 143, 5610-5615. → link
Shun Kimura, Motoyuki Uejima, Wataru Ota, Tohru Sato, Shinpei Kusaka, Ryotaro Matsuda, Hiroshi Nishihara*, and Tetsuro Kusamoto*
"An Open-shell, Luminescent, Two-Dimensional Coordination Polymer with a Honeycomb Lattice and Triangular Organic Radical" J. Am. Chem. Soc.2021, 143, 4329-4338. → link
Shun Kimura, Shojiro Kimura, Ken Kato, Yoshio Teki*, Hiroshi Nishihara*, and Tetsuro Kusamoto*
"A ground-state-dominated magnetic field effect on the luminescence of stable organic radicals" Chem. Sci.2021, 12, 2025-2029. Selected as a part of the themed collection: 2020 Chemical Science HOT Article Collection→ link Selected as the Inside Front Cover → link
Sara Mattiello, Francesca Corsini, Sara Mecca, Mauro Sassi, Riccardo Ruffo, Giuseppe Mattioli, Yohei Hattori, Tetsuro Kusamoto,* Gianmarco Griffini,* and Luca Beverina*
"First demonstration of the use of stable open shell derivatives as organic luminophores for transparent Luminescent Solar Concentrators" Mater. Adv.2021, 2, 7369-7378. → link
Yohei Hattori,* Shunsuke Tsubaki, Ryota Matsuoka, Tetsuro Kusamoto, Hiroshi Nishihara, and Kingo Uchida*
"Expansion of Photostable Luminescent Radicals by Meta-Substitution" Chem. Asian J.2021, 16, 2538-2544. → link
Ryo Yoshimoto, Satoshi Yamashita, Hiroki Akutsu, Yasuhiro Nakazawa*, Tetsuro Kusamoto, Yugo Oshima, Takehito Nakano, Hiroshi M. Yamamoto, and Reizo Kato
"Electric dipole induced bulk ferromagnetism in dimer Mott molecular compounds" Sci. Rep.2021, 1332. → link
2020
Shun Kimura, Shojiro Kimura, Hiroshi Nishihara*, and Tetsuro Kusamoto*
"Excimer emission and magnetoluminescence of radical-based zinc(II) complexes doped in host crystals" Chem. Commun.2020, 56, 11195-11198. Selected as a part of the themed collection: 2020 Emerging Investigators → link Selected as the Inside Front Cover → link
Chie Ohde, Tetsuro Kusamoto*, and Hiroshi Nishihara*
"Effects of halogen atom replacement on the structure and magnetic properties of a molecular crystal with supramolecular two-dimensional network mediated via sulfur's σ-holes" J. Magn. Magn. Mater.2020, 497, 165986. → link
Ryosuke Miyake*, Eri Suganuma, Shun Kimura, Hirotoshi Mori, Jun Okabayashi, and Tetsuro Kusamoto
"Cyclic heterometallic interactions formed from a flexible tripeptide complex showing effective antiferromagnetic spin coupling" Angew. Chem. Int. Ed.2020, 60, 5179-5183. → link
Hiroaki Maeda, Aayushi Bajpayee, Tetsuro Kusamoto, and Hiroshi Nishihara
"Construction of Bis(2,6-bis(1-methylbenzimidazol-2-yl)pyridine)iron(II) Coordination Polymer for Incorporation of Magnetic Function" JIOPM2020, 30, 147-152. → link
2019
Shun Kimura, Hikaru Uchida, Tetsuro Kusamoto*, and Hiroshi Nishihara*
"One-dimensional magnetic chain composed of CuII and polychlorinated dipyridylphenylmethyl radical: temperature-dependent Jahn-Teller distortion correlated to π-conjugation and magnetic properties" Dalton Trans.2019, 48, 7090-7093. Selected as a HOT article → link
Akira Tanushi, Shun Kimura, Tetsuro Kusamoto*, Moe Tomonaga, Yasutaka Kitagwa, Masayoshi Nakano, and Hiroshi Nishihara*
"NIR Emission and Acid-Induced Intramolecular Electron Transfer Derived from a SOMO-HOMO Converted Non-Aufbau Electronic Structure" J. Phys. Chem. C2019, 123, 4417-4423. → link
Ken Kato, Shun Kimura, Tetsuro Kusamoto*, Hiroshi Nishihara*, and Yoshio Teki*
"Luminescent Radical‐Excimer: Excited‐State Dynamics of Luminescent Radicals in Doped Host Crystals" Angew. Chem. Int. Ed.2019, 58, 2606-2611. Selected as a HOT paper → link
Tetsuro Kusamoto* and Hiroshi Nishihara*
"Zero-, one- and two-dimensional bis(dithiolato)metal complexes with unique physical and chemical properties" Coord. Chem. Rev.2019, 380, 419-439. → link
Toyohiro Usui, Zhendong Liu, Hirokazu Igarashi, Yukichi Sasaki, Yuji Shiramata, Hiroki Yamada, Koji Ohara, Tetsuro Kusamoto, and Toru Wakihara*
"Identifying the Factors Governing the Early-Stage Degradation of Cu-Chabazite Zeolite for NH3-SCR" ACS Omega2019, 4, 3653-3659. → link
Hiroshi Okada, Hiroshi Ueno, Yasuhiro Takabayashi, Takeshi Nakagawa, Martina Vrankic, John Arvanitidis, Tetsuro Kusamoto, Kosmas Prassides*, and Yutaka Matsuo*
"Chemical reduction of Li+@C60 by decamethylferrocene to produce neutral Li+@C60•-" Carbon2019, 153, 467-471. → link
Selected publications before 2018
Tetsuro Kusamoto* and Hiroshi Nishihara*
"Efficiency breakthrough for radical LEDs" Nature2018, 563, 480-481. NEWS AND VIEWS→link
Shun Kimura, Tetsuro Kusamoto*, Shojiro Kimura, Ken Kato, Yoshio Teki, and Hiroshi Nishihara*
"Magnetoluminescence in a Photostable, Brightly Luminescent Organic Radical in a Rigid Environment" Angew. Chem. Int. Ed.2018, 57, 12711-12715. Selected as VIP→link→Inside cover
Shun Kimura, Akira Tanushi, Tetsuro Kusamoto*, Shuntaro Kochi, Tohru Sato, and Hiroshi Nishihara*
"A Luminescent Organic Radical with Two Pyridyl Groups: High Photostability, Dual Stimuli-Responsive Property, and Theoretical Analyses of Photophysical Processes" Chem. Sci.2018, 9, 1996-2007. →link
Yohei Hattori, Shun Kimura, Tetsuro Kusamoto*, Hiroaki Maeda, and Hiroshi Nishihara*
"Cation-responsive turn-on fluorescence and absence of heavy atom effects of pyridyl-substituted triarylmethyl radicals" Chem. Commun.2018, 54, 615-618. →link
Chie Ohde, Tetsuro Kusamoto*, Koji Nakabayashi, Shin-ichi Ohkoshi, Hiroshi Nishihara*
"Supramolecular Two-Dimensional Network Mediated via Sulfur's σ-Holes in a Conducting Molecular Crystal: Effects of Its Rigidity on Physical Properties and Structural Transition" Cryst. Growth Des.2017, 17, 2230-2210. →link
Yasuyo Ogino, Tetsuro Kusamoto*, Yohei Hattori, Masaki Shimada, Mizuho Tsuchiya, Yoshinori Yamanoi, Eiji Nishibori, Kunihisa Sugimoto, Hiroshi Nishihara*
"Solvent-Controlled Doublet Emission of an Organometallic Gold(I) Complex with a Polychlorinated Diphenyl(4-pyridyl)methyl Radical Ligand: Dual Fluorescence and Enhanced Emission Efficiency" Inorg. Chem.2017, 56, 3909-3915. →link
Yohei Hattori, Tetsuro Kusamoto*, Tohru Sato, Hiroshi Nishihara*
"Synergistic Luminescence Enhancement of a Pyridyl-substituted Triarylmethyl Radical Based on Fluorine Substitution and Coordination to Gold" Chem.Comm.2016, 52, 13393-13396. →link
Tetsuro Kusamoto*, Shun Kimura, Yasuyo Ogino, Chie Ohde, Hiroshi Nishihara*
"Modulated Luminescence of a Stable Open-shell Triarylmethyl Radical: Effects of Chemical Modification on its Electronic Structure and Physical Properties" Chem. Eur. J.2016, 22, 17725-17733. →link
Tetsuro Kusamoto*, Shun Kimura, Hiroshi Nishihara*
"Structural and Magnetic Investigations of a Heterospin System Composed of High-spin Mn(II) and Pyridyl-containing Triarylmethyl Radicals" Chem Lett. 2016, 45, 1057-1059. →link
Yohei Hattori, Tetsuro Kusamoto*, Hiroshi Nishihara*
"Highly Photostable Luminescent Open-shell (3,5-Dihalo-4-pyridyl)bis(2,4,6-trichlorotrichlorophenyl)methyl Radicals: Significant Effects of Halogen Atoms on Their Photophysical and Photochemical Properties" RSC Adv.2015, 5, 64802-64805. →link
Akira Tanushi, Tetsuro Kusamoto*, Yohei Hattori, Kenji Takada, Hiroshi Nishihara*
"Spin-Reconstructed Proton-Coupled Electron Transfer in a Ferrocene-Nickeladithiolene Hybrid" J. Am. Chem. Soc.2015, 137, 6448-6451. →link
Tetsuro Kusamoto*, Yohei Hattori, Akira Tanushi, Hiroshi Nishihara*
"Intramolecular Ferromagnetic Radical-CuII Coupling in a CuII Complex Ligated with Pyridyl-Substituted Triarylmethyl Radicals" Inorg. Chem. 2015, 54, 4186-4188. →link
Yohei Hattori, Tetsuro Kusamoto*, Hiroshi Nishihara*
"Enhanced Luminescent Properties of an Open-Shell (3,5-Dichloro-4-pyridyl)bis(2,4,6-trichlorophenyl)methyl Radical by Coordination to Gold" Angew. Chem. Int. Ed2015, 54, 3731-3734. →link
Yohei Hattori, Tetsuro Kusamoto*, Hiroshi Nishihara*
"Luminescence, Stability, and Proton Response of an Open-Shell (3,5-Dichloro-4-pyridyl)bis(2,4,6-trichlorophenyl)methyl Radical" Angew. Chem. Int. Ed2014, 53, 11845-11848. →link
Tetsuro Kusamoto*, Hiroshi Nishihara, Reizo Kato
"Substituent-Dependent Spin-Density Distribution and Coexistence of Fe 3d and π Spins on Ferrocene-Tetrathiafulvalene Hybrids" Inorg. Chem.2013, 52, 13809-13811. →link
Tetsuro Kusamoto*, Hiroshi M. Yamamoto, Reizo Kato
"Utilization of σ-Holes on Sulfur and Halogen Atoms for Supramolecular Cation-Anion Interactions in Bilayer Ni(dmit)2 Anion Radical Salts" Cryst. Growth Des.2013, 13, 4533-4541. →link
Tetsuro Kusamoto*, Hiroshi M. Yamamoto, Naoya Tajima, Yugo Oshima, Satoshi Yamashita, Reizo Kato
"Bilayer Mott System with Cation…Anion Supramolecular Interactions Based on Nickel Dithiolene Anion Radical:Coexistence of Ferro- and Antiferromagnetic Anion Layers and Large Negative Magnetoresistance" Inorg. Chem.2013, 52, 4759-4761. →link
Tetsuro Kusamoto, Kenji Takada, Ryota Sakamoto, Shoko Kume, Hiroshi Nishihara*
"Ferrocene-Dithiolene Hybrids: Control of Strong Donor-Acceptor Electronic Communication to Reverse the Charge Transfer Direction" Inorg. Chem.2012, 51, 12102-12113. Selected as a Cover Art→link
Tetsuro Kusamoto,* Hiroshi M. Yamamoto, Naoya Tajima, Yugo Oshima, Satoshi Yamashita, Reizo Kato
"Bilayer Mott System Based on Ni(dmit)2 (dmit = 1,3-dithiole-2-thione-4,5-dithiolate) Anion Radicals: Two Isostructural Salts Exhibit Contrasting Magnetic Behavior" Inorg. Chem.2012, 51, 11645-11654. →link
Tetsuro Kusamoto, Shoko Kume, Hiroshi Nishihara*
"Cyclization of TEMPO Radicals Bound to Metalladithiolene Induced by SOMO-HOMO Level Conversion" Angew. Chem. Int. Ed.2010, 49, 529-531. →link
Tetsuro Kusamoto, Jaime Ruiz, Didier Astruc*
"Towards Molecular Batteries: Coverage of Small Aminosilica Nanoparticles with Ferrocenyl and Pentamethylferrocenyl Groups and Their Redox Properties" New. J. Chem.2009, 33, 2204-2207. →link
Tetsuro Kusamoto, Shoko Kume, Hiroshi Nishihara*
"Realization of SOMO-HOMO Level Conversion for a TEMPO-Dithiolate Ligand by Coordination to Platinum(II)" J. Am. Chem. Soc.2008, 130, 13844-13845. →link
Tetsuro Kusamoto, Emiko Fujiwara, Akiko Kobayashi,*
"Molecule-based Weak Ferromagnet with Unique Magnetic Multiphases" Chem. Lett.2005, 36, 858-859. →link
Presentations
2022
Tetsuro Kusamoto ''Spin-correlated Photofunctions Based on Luminescent Radicals'' Institute for Materials Research International Symposium (Tohoku University, Sendai, Japan), Oct. 8, 2022. 招待講演
Tetsuro Kusamoto ''An open-shell, magnetoluminescent, two-dimensional coordination polymer with a triangular organic radical ligand'' 8th Asian Conference on Coordination Chemistry (ACCC8 2022) (online, Taipei, Taiwan) August 10, 2022. 招待講演
Ryota Matsuoka, Tetruto Kusamoto, ''Magnetic Field Effect on the Luminescence of Stable Radicals at the Single-Molecular Level'' 7th Kanto Area Spin Chemistry Meeting (KASC 2021) (Online) Dec. 18, 2021.
Tetsuro Kusamoto, ''A Cu(II)-radical heterospin magnetic chain: temperature-dependent Jahn-Teller distortion correlated to π-conjugation and magnetic properties'' RSC Dalton Transactions New Talent: Asia-Pacific Desktop Seminar (Online) Feb. 2nd, 2021. 招待講演
Tetsuro Kusamoto, Shun Kimura, Hikaru Uchida, Hiroshi Nishihara ''Stimuli-Responsive Photonic, Electronic, and Magnetic Functions in Pyridyl-Containing Luminescent Radicals''The 1st Asian Conference on Molecular Magnetism (ACMM) (Online, Fukuoka) March 8, 2021.
Tetsuro Kusamoto, ''Luminescence and Structure-Magnetism Correlation of Open-Shell Metal Complexes'' 7TH ASIAN CONFERENCE ON COORDINATION CHEMISTRY (ACCC7) (Putra World Trade Centre, Kuala Lumpur, Malaysia), October 15, 2019. 招待講演
Tetsuro Kusamoto, ''Magnetoluminescence in photostable radicals'' Spin Chemistry Meeting 2019 (Courtyard by Marriott West Pushkin Hotel, St. Petersburg, Russia), August 17, 2019. 招待講演
Shun Kimura, Tetsuro Kusamoto, Shojiro Kimura, Ken Kato, Yoshio Teki, Hiroshi Nishihara ,''Magnetic Field Effect on the Luminescence of Stable Radicals in a Rigid Environment'' Spin Chemistry Meeting 2019 (Courtyard by Marriott West Pushkin Hotel, St. Petersburg, Russia), August 17, 2019.
Tetsuro Kusamoto, ''Magnetic field effect on emission spectrum and lifetime of a PyBTM radical doped into host crystals'' 4th Kanto Area Spin Chemistry Meeting (KASC 4th meeting) (Gunma University, Kiryu, Japan), Nov. 24, 2018. 招待講演
Tetsuro Kusamoto, ''Chemically-controlled luminescence and magnetism of stable radicals'' Rising star ICMM2018 Pre-Conference (Windsor Marapendi Hotel, Rio de Janeiro, Brazil), Sep. 1, 2018. 招待講演
Tetsuro Kusamoto, ''Development and magnetic field effect of luminescent stable radicals'' 3rd KASC meeting (Kanagawa University, Kanagawa), Dec. 16, 2017. 招待講演
Tetsuro Kusamoto, ''Photostable Fluorescent Radicals: Modulated Luminescence by Coordination to Metal'' 8th Pacific Symposium on Radical Chemistry (PSRC-8) (QUT, Brisbane, Queensland, Australia), July 21, 2017. 招待講演
Tetsuro Kusamoto, ''Stimuli-Responsive Fluorescent Radicals'' International Symposium on Pure & Applied Chemistry (ISPAC2017), POC06, Ho Chi Minh City (HCMC), Vietnam., Jun. 9, 2017. 招待講演
Tetsuro Kusamoto, ''Enhanced fluorescence in stable organic radicals'' ETHZ-UTokyo Joint Symposium of Frontier Chemistry (The Univ. of Tokyo, Tokyo, Japan), Nov. 9, 2016. 招待講演
Tetsuro Kusamoto, ''Luminescent Open-Shell Organic Radicals and the Metal Complexes'' International Conference on Coordination Chemistry 2016 (ICCC2016) S6.IS6 (Le Quartz Congres, Brest, France), July 7, 2016. 招待講演
Tetsuro Kusamoto, ''Highly Photostable Luminescent Organic Radicals and the Metal Complexes'' 13th Materials Science School for Young Scientists -Rising Star Pre-ICMM@IMR- (IMR, Sendai, Japan) Sep. 4, 2016. 招待講演